Mixed polyalkylene glycol polyphosphorus compound

ABSTRACT

MIXED POLYALKYLENE GLYCOL POLYPHOSPHOROUS COMPOUNDS CONTAINING BOTH PHOSPHITE AND VINYL PHOSPHATE LINKAGES ARE PREPARED BY REACTING CERTAIN POLYALKYLENE GLYCOL POLYPHOSPHITES WITH LESS THAN A STOICHIOMETRIC AMOUNT OF A HALOGENATED CARBONYL COMPOUND.

States Patent once Patented Mar. 19, 1974 3,798,290 MIXED POLYALKYLENE GLYCOLPOLY- PHOSPHORUS COMPOUND Kyung S. Shim, Irvington, N.Y., assignor to Stanfiel- Chemical Company, New York, N.Y.

No Drawing. Continuation-impart of application Ser. No. .w

86,313, Nov. 2, 1970, which is a continuation-in-part of application Ser. No. 63,262, Aug. 6, 1970, now abandoned. This application July 26, 1971, Ser. No.

Int. Cl. C07f 9/08; C08g 22/44 US. Cl. 260-929 ABSTRACT OF THE DISCLOSURE Mixed polyalkylene glycol polyphosphorus compounds containing both phosphite and vinyl phosphate linkages are prepared by reacting certain polyalkylene glycol polyphosphites with less than a stoichiometric amount of a halogenated carbonyl compound.

RELATED APPLICATION This application is a continuation-in-part of application Ser. No. 86,313, filed Nov. 2, 1970 which in turn is a continuatiou-in-part of application Ser. No. 63,262, filed Aug. 6, 1970 by Kyung Sup Shim, now abandoned.

BACKGROUND OF THE DISCLOSURE fire retardant agent can be copolymerized into the polymer chain. One such group of reactiveflame retardants are the polyalkylene glycol phosphites such as those described in US. Pat. No. 3,009,939. However, these materials, due to their high OH numbers and crosslinking tendency, are unsuitable for use in flexible urethane foams. In US. Pats. 3,081,331 and 3,142,651, there is disclosed a method of forming polyalkylene glycol polyphosphites having up to 10 phosphite groups in thepolymer chain by reacting a trialkyl phosphite with a polypropylene glycol in a molar ratio of 2.1 to 2.5 moles of glycol per mole of phosphite. These materials are also unsuitable for use in flexible urethane foams as a result of their high OH numbers and their tendency to crosslink.

Another attempt at employing reactive flame retardants described in US. 3,142,651 and 3,092,651, involves the use of polypropylene glycol poly-hydrogenphospho nates produced by a thermal polymerization. Likewise, polyalkylene glycol hydrogen polyphosphonates have also been produced by transesterifying a secondary hydrogen phosphonate with a polyalkylene glycol according to the procedure outlined in British Pats. Nos. 796,446 and 1,011,118. However, many of these materials have relatively high acidity, causing them to react with and thereby deactivate certain catalyst systems generally used in the formation of polyurethane polymers such, for example, as tertiary amine compounds. The first method has the additional drawback of contamination of the product by the alkylene glycol by-product, which contamination is not easily removed.

In order to increase the flame retardncy of some of the above described phosphorus compounds, which have low phosphorus content, the prior art has attempted to incorporate various halogen containing substituents into the above described molecules. Thus US. Pat. 3,159,605 describes the reaction of halogenated methanes with 5 Claims these compounds. Likewise U.S. Pats. 3,131,206 and 3,- 328,493 describe the reaction of chloral with them. However, these materials, like their precursors, have many drawbacks. In particular these products have high OH numbers and low phosphorus content thereby rendering them unsuitable as flame retardants in flexible urethane foams.

In the above cited co-pending U.S. applications, there are disclosed novel polyalkylene glycol vinyl phosphates which are far superior as flame retardants for urethane foams, particularly flexible foam, than any of the above described flame retardants. These vinyl phosphates, however, have one drawback. While they yield foams having excellent flame retardance and physical characteristics, they tend to discolor the center of the bun, thereby rendering the foam objectionable in appearance.

It is an object of the present invention to prepare novel polyalkylene glycol polyphosphorus compounds which are suitable as flame retardants for urethane foams, and in particular flexible urethane foams.

It is another object of the present invention to prepare novel polyalkylene glycol polyphosphorus compounds which, while exhibiting flame retardancy and physical properties comparable with those of the flame retardants described in the above cited co-pending applications, yield foams having good color and appearance throughout. Further advantages of the present invention will become obvious from a reading of the disclosure which follows hereinafter.

TECHNICAL DESCRIPTION OF THE DISCLOSURE It has now been discovered that, by reacting a halogenated carbonyl compound with certain polyalkylene glycol polyphosphites in an amount less than the stoichiometric equivalent, there is obtained a polyalkylene glycol polyphosphorus compound having both phosphite and vinylphosphate linkages along the polymer chain. These polyalkylene glycol polyphosphorus compounds, when incorporated into urethane foams, yield foams having superior flame retardance, physical properties, and little if any discoloration in the bun.

The polyalkylene glycol polyphosphorus compounds of the present invention are polymers containing both phosphite and vinylphosphate linkages. They are characterized by low OH numbers and acidity, a lack of the tendency to gel initially or crosslink in the final foamed product, and high stability during and subsequent to the foam forming process. These compounds can be represented wherein R is a polyalkylene glycol residue; R is either hydrogen, alkyl or haloalkyl; Z and Y are each either hydrogen, halogen, or alkyl; R is an alkyl residue from the tertiary phosphite used to produce the polyalkylene glycol alkyl polyphosphite starting material of the present invention; m and n are numbers in the range between from 1 to about 25 such that the sum of m+n is from about 2 to about 50, and preferably between about 4 to about 10. In the above formula, when any of R, Y and Z are an alkyl or haloalkyl group, they preferably contain from 1 to about 4 carbon atoms. The term alkyl residue as designated by R is preferably C alkyl and most preferably methyl or ethyl. The term halogen and the prefix halo are meant to designate either chlorine or bromine. The term polyalkylene glycol residue, designated by wherein R is an alkylene group of from 2 to about 20 carbon atoms, which is straight chained, branch chained, or a mixture thereof, and x designates the number of repeating alkylene ether units and is normally from 2 to about 20.

The formula for the polyphosphorus compounds shown above, as will be readily appreciated by those skilled in the art, is meant to designate a mixed polymer wherein the phosphite and phosphate linkages are randomly dispersed along the polymer chain. Furthermore, it is understood that the formula encompasses mixtures of polymers having an average chain length of m-l-n wherein m and n each represent an average value of the number of phosphite and phosphate linkages contained in this mixture rather than just a single pure compound.

The compounds of the present invention are produced by reacting a halogenated carbonyl compound with a polyalkylene glycol alkyl polyphosphite which has an idealized formula as follows:

(|)R1 ORO-P H ORO/m+n wherein R, R m and n are as described as above. This polyphosphite, in turn, is formed by transesterifying a tertiary phosphite with a polyalkylene glycol in a molar ratio of from about 1 to about 1.5 and preferably from 1 to 1.2 moles of phosphite per mole of glycol.

The tertiary phosphite used to prepare the polyalkylene glycol alkyl polyphosphite starting material has the general formula:

wherein each R is as defined above. The phosphites used can be chosen from the following: trimethyl phosphite, triethyl phosphite, tripropyl phosphite, tributyl phosphite, trioctyl phosphite, dimethyl ethyl phosphite, diethyl methyl phosphite, and the like. Trimethyl and triethyl phosphite are particularly preferred, with trimethyl phosphite being most preferred.

The above described tertiary phosphite is transesterified with a polyalkylene glycol having the formula:

wherein R and x are as described above. Illustrative of the polyalkylene glycols which can be employed in the present invention are the following: diethylene glycol, triethylene glycol, dipropylene glycol, tripropylene glycol, tributylene glycol, polyethylene glycols wherein the average number of ether units is 2, polypropylene glycols wherein the average number of ether units is 14, trihexylene glycol and the like. Particularly preferred glycols are diethylene glycol, dipropylene glycol and tripropylene glycol. It is understood that these propylene glycols can be primary, secondary or mixtures thereof.

In order to form the polyphosphite starting materials of the present invention, the tertiary phosphite and the polyalkylene glycol must be reacted in critical proportions. Thus, the phosphite should be present in an amount from about 1 to about 1.5 moles per mole of the glycol. The preferred range for this preparation is from about 1 to about 1.2 moles of phosphite per mole of glycol. If the glycol is reacted in quantities greater than 1 to 1 with the phosphite, the product will contain primarily the undesirable mono, di, tri and tetraphosphites and, more importantly, will have a substantial amount of free alkylene hydroxyl groups attached to the phosphite group.

The above disclosed transesterification reaction is normally conducted by mixing the phosphite and glycol in the presence of any of the well-known transesterification catalysts. Particularly useful catalysts are the alkali metal alcoholates and phenolates such 'as sodium methylate, sodium decylate, sodium phenolate, and the like. These catalysts are normally employed in an amount from about 0.01 to about 10 percent, by weight, of the entire reactant mixture. The reaction temperature should initially be kept below the boiling point of the lowest boiling reactant in order to avoid the loss of that reactant. Although the reaction can be conducted at room temperature, i.e. 20 C., it is preferred to conduct it as close to the upper limit as possible in order to increase the rate of reaction. Thus, in the case where trimethyl phosphite is employed as the tertiary phosphite, the reaction temperature is preferably within the range of C. to C. and should not be allowed to rise above C. until at least one R group on each of the phosphite molecules has been replaced with a polyalkylene glycol. This can normally be determined by monitoring the amount of methanol which has been evolved.

While the reaction can be run to completion at these temperature ranges, it has been found to be advantageous to raise the temperature after this initial replacement of one of the R groups on the starting phosphite up to a limit of about 200 C. and most preferably up to about C. As stated above, the point at which the temperature should be raised can be determined by monitoring the amount of by-product alkanol produced. Thus, when one mole of trimethyl phosphite is being transesterified, the reaction temperature can be raised after one mole of methanol has been evolved. The transesterification is completed when two moles of methanol have been evolved. The degree of polymerization of the polyphosphite can be controlled to an extent by varying the time of the reaction. Furthermore, the polymer length can be monitored by measuring the viscosity buildup during the reaction according to well-known techniques.

The transesterification reaction can optionally be carried out in the presence of an inert solvent, however, such solvent is not required for the practice of the present invention. The term inert solvent is meant to designate any solvent which does not react with the starting materials or products of the present invention. Suitable solvents include the alkylated benzenes such as ethyl benzene, diethyl benzene, toluene, the xylenes, and the like.

The polyalkylene glycol alkyl polyphosphites produced by the process described above is then reacted with a halogenated carbonyl compound having the formula:

0 x Z R JLB where R, Z and Y are as defined above and X is bromine or chlorine. These carbonyl compounds can be illustrated by the following: chloral, bromal, 1,1,1-trichloroacetone, 1,1,l-tribromoacetone, hexachloroacetone, hexabromoacetone, pentachloroacetone, monochloroacetone, monobromoacetone, dichloroacetaldehyde, dibromoacetaldehyde, chloroacetaldehyde, bromoacetaldehyde, chloromethyl ethyl ketone, dichloromethyl ethyl ketone, trichloromethyl ethyl ketone, bromomethyl ethyl ketone and the like. Preferred carbonyl compounds are chloral, bromal, monochloroacetone, monobromoacetone, trichloroacetone, tribromoacetone, pentachloroacetone, hexachloroacetone, dichloroacetaldehyde and chloromethyl ethyl betone. Particularly preferred compounds for use in the present invention are chloral, bromal, monochloroacetone and monobromoacetone.

The carbonyl compound is reacted with the polyphosphite in less than a stoichiometric quantity. The term, stoichiometric quantity as used herein, is meant to designate the molar equivalent of phosphite groups in the polyphosphite. By employing less than this quantity, the product will contain unreacted phosphite groups, which stabilize the urethane foam into which it has been incorporated against changes in color. While employing an amount of carbonyl compound less than a stoichiometric quantity will have a color stabilizing efl ect, the optimum results can be achieved by balancing the flame retardant properties of the vinyl phosphate with the stabilizing properties of the phosphite. The normal range for more foam applications is from about 0.1 to about 0.9 mole of carbonyl compound per mole of phosphite group. The most preferred range for flexible urethane foams is from about 0.6 to about 0.9 mole of carbonyl compound per mole of phosphite group.

The carbonyl compound can be reacted with the polyphosphite over a wide temperature range. Normally temperatures from about 0 to about 150 C. are employed, with the preferred range being from about 20 to about 85 C. The reaction can be monitored by determining the amount of alkyl halide by-product formed. Thus, when 0.6 molar equivalent of carbonyl compound is used, the reaction is completed when 0.6 mole of alkyl halide has evolved.

The reaction with the carbonyl compound is preferably carried out in the presence of a solvent or diluent although this is not necessary to the invention. The solvent helps to control the temperature of the reaction, which is very exothemic in nature, and thereby, eliminates the necessity of cooling the reactants to maintain the proper reaction temperature. The solvent or diluent should be non-reactive with respect to both the starting materials and the desired products, and should be miscible therewith. Illustrative of suitable solvents are benzene, xylene, ethylbenzene, diethylbenzene, various alkanes, and the like.

The novel compounds. of the present invention are characterized by their ability to copolymerize with polyisocyanates employed in forming polyurethanes, by their relatively low OH members and acidity, by their high phosphorus content, and by their high flame retardancy and stabilizing characteristics in the final foams. These compounds can completely replace the polyols normally employed in forming the foams or they can be used in combination with the polyols, thereby yielding foams with greatly improved flame resistance. Since they react in the foam forming process, their residues are chemically bonded into the foam, thereby giving them high permanance, even upon high temperature aging. The acid numbers of the compounds of the present invention are normally below about 2 milligrams of KOH per gram of the polyalkylene glycol polyphosphorus compound. This low acidity makes these compounds relatively unreactive toward the polymerization catalysts employed in producing the polyurethane foams. The vinyl phosphate groups in these compounds reduces the concentration necessary to achieve a flame resistant foam, while the phosphite group stabilizes the foam against discoloration. As mentioned above, these compounds have relatively low OH numbers as compared to the prior art flame retardants and, therefore, can be used in flexible urethane foams without materially affecting the physical properties of such foams. By the term relatively low 0H numbers, it is meant to designate 0H numbers below about 150 and preferably below 100.

The compounds of the present invention are further characterized by the fact that they are substantially linear polymers when compared to those disclosed in the prior art. This results, at least in part, from the fact that the intermediate polyalkylene glycol alkyl polyphosphites used to make the present compounds contain primarily alkyl side chains attached to the phosphite groups. Consequently, the labile halogen released by the attacking carbonyl compound will preferentially react with the alkyl side chain rather than with the glycol linking groups. Thus, it has been observed that the by-product formed by the addition of the carbonyl compound to the polyphosphite intermediate used herein is the alkyl halide rather than the 6 halogenated polyether alcohol which would result from attack on the polyalkylene glycol. Since the phosphite alkyl group is attacked preferentially there is little or no depolymerization.

An additional advantage inherent in the present invention is the fact that the alkyl halide by-product can easily be separated from the desired final product whereas a halogenated polyether alcohol by-product such as would be formed when using the polymers described in US. 3,328,493, cannot be easily separated due to its higher boiling point. Furthermore, the necessity for separating a halogenated polyether alcohol by-product such as would be formed by 3,328,493 is manifest since it is a monofunctional alcohol which would seriously impair, if not destroy, the foam forming ability of the urethane foam rrux.

The compounds of the present invention, when employed in sufficient quantity, will yield a self-extinguishing polyurethane foam. This characteristic is particularly important in the area of flexible foams due to the wide use of such foams in hospitals, homes and automobiles. Normally, the compounds of the present invention can be employed in amounts of from about 5 to about 30 percent, by weight, of the entire foam forming mixture to yield self-extinguishing flexible foams. Preferably they are employed in amounts from 10 to 15 percent, by weight, of the entire mixture. It is understood, however, that this amount will vary depending upon the particular foam being used, and that the required proportions can easily be determined with a minimum amount of blending work.

While the compounds of the present invention are primarily intended for use in urethane foams, it is contemplated that they can also be used in a wide variety of polymeric systems. Illustrative of these systems are: polyesters, polyolefins, cellulose ethers and esters, urethane coatings and elastomers, polymethyl methacrylates, polyvinyl chlorides, and many others. Furthermore, the compounds of the present invention can also be employed in combination with any of the known flame retardants in foams or polymeric systems.

The polyurethane foams within which the flame retardants described above are incorporated are well known in the art. They are produced by the reaction of a dior polyisocyanate and a dior polyhydroxy (polyol) compound in the presence of a blowing agent and a catalyst. The foams can be made by any of the basic techniques used in foam formation; i.e., the prepolymer technique, the semi-prepolymer technique or the one-shot process. These techniques are well known and described in the polyurethane art.

As examples of organic diand polyisocyanates which can be employed to make the polyurethane foams there can be employed toluene-2,4-diisocyanate; toluene-2,6- diisocyan-ate; 4-methoxy-1,3-phenylene diisocyanate; diphenyl methane-4,4'-diisocyanate; 4-chloro-1,3-phenylenediisocyanate; 4-isopropyl-1,3 phenylene-diisocyanate; 4- ethoxy-1,3 phenylene-diisocyanate; 2,4 diisocyanate-diphenylether; 3,3'-dimethyl 4,4 diisocyanate-odiphenyl methane; mesitylene diisocyanate; durylene diisocyanate; 4,4-methylene-bis (phenylisocyanate); benzidine diisocyanate; o-nitrobenzidine diisocyanate; 4,4-diisocyanate-dibenzyl; 3,3'-bitolylene-4,4'-diisocyanate; 1,5 naphthalene diisocyanate; tetramethylene diisocyanate; hexamethylene diisocyanate; decamethylene diisocyanate; toluene-2,4,6- triisocyanate; tritolylmethane triisocyanate; 2,4,4'-triisocyanatodiphenyl ether; the reaction product of toluene diisocyanate with trimethylolpropane; and the reaction product of toluene diisocyanate with 1,2,6-hexanetriol.

Alternatively, as the polyisocyanate there can be used prepolymers made by reacting one or more of the above polyisocyanates with a dior polyhydroxy compound such as a polyester having terminal hydroxyl groups, a polyhydric alcohol, glycerides or hydroxy containing glycerides, etc. These prepolymers should have terminal isocyanate groups and, to insure their presence, it is frequently desirable to employ an excess of or more of the polyisocyanate in forming the prepolymer. Typical examples of such prepolymershaving isocyanate end groups are those formed from toluene diisocyanate and polyhydroxy compounds. In most cases, a mixture of 80% of the 2,4-isomer and 20% of the 2,6-isomer of toluene diisocyanate is employed in making these prepolymers. Thus, there can be used the prepolymers resulting from the reaction between toluene diisocyanate and caster oil, blown tung oil, blown linseed oil or blown soya oil, and of toluene diisocyanate and the polyester of ethylene glycol, propylene glycol and adipic acid.

Examples of suitable polyols are polyethylene glycol, polypropylene glycols, ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol, tripropylene glycol, 1,4-butanediol, thiodiglycol, glycerol, trimethylolethane, trimethylolpropane, ether triols from glycerine and propylene oxide, other containing triols from 1,2,6-hexanetriol and propylene oxide, sorbitolpropylene oxide adducts, pentaerythritol-propylene oxide adducts, trimethylol phenol, oxypropylated sucrose, triethanolamine, pentaerythritol, diethanolamine, castor oil, blown linseed oil, blown soya oil, N,N,N',N-tetrakis(2- hydroxyethyl) ethylenediamine, N,N,N',N'-tetrakis(2ehydroxypropyl) ethylenediamine, N,N,N',N",N",-pentakis (Z-hydroxypropyl) diethyl tria'mine, N,N, N,N"',N"-"

pentakis(2-hydroxyethyl) diethylene 'triamine, mixed ethylene glycol-propylene glycol adipate resin, polyethylene adipate phthalate and polyneopentylene sebacate.

In preparing the foamed polyurethanes there can be used any of the conventional basic catalysts such, for example, as N-methyl morpholine, N-ethyl morpholine, 1,2,4-trimethylpiperazine, trimethyl amine, triethyl amine, tributyl amine and other trialkyl amines, the esterification product of adipic acid and diethylethanolamine, triethyl amine citrate, 3-morpholinopropionamide, 1,4 bis(2hydroxypropyl) -2-methylpiperazine, Z-diethylaminoacetamide, S-diethylaminopropionamide, diethylethanolamine, triethylenediamine, N,N,N',N'-tetrakis (2- hydroxypropyl) ethylenediamine, vN,N-dimethylpipe'razine, N,N-dimethylhexahydroaniline, tribenzylamine and sodium phenolate. Also, applicable are tin compounds,-

e.g. hydrocarbon tin acrylates such as dibutyltin dilaurate, dibutyltin diacetate, dibutyltin dioctoate, tributyltin monolaurate, dimethyltin diacetate, diocyltin diacetate, dilauryltin diacetate, dibutyltin maleate, hydrocarbon tin alkoxides, e.g. dibutyltin diethoxide, dibutyltin dimethoxide, diethyltin dibutoxide as well as other tin compounds, e.g. octylstannoic acid, trimethyltin hydroxide, trimethyltin chloride, triphenyltin hydroxide, trimethyltin chloride, triphenyltin hydride, triallyltin chloride, trioctyltin fluoride, dibutyltin dibromide, bis-(carboethoxymethyl) tin diiodide, tri butyltin chloride, trioctyltin acetate, butyltin trichloride, octyltin tris(thiobutoxide), dimethyltin oxide, dibntyl tin oxide, dioctyltin oxide, dphenyltin oxide, stannous octanoate, and stannous oleate.

Any of the conventional surfactants can be used in amounts of 1% or less, e.g. 0.2% by weight of the composition. The preferred surfactants are silicones, e.g. polydimethyl siloxane having a viscosity of 3 to 100 centistokes, triethoxydimethyl polysiloxane, molecular weight 850 copolyrnerized with a dimethoxypolyethylene glycol having a molecular weight of 750.

The foaming reaction can be carried out by adding water to the polyol prior to or simultaneously with the prepared by the use of a foaming or blowing agent. These are usually a liquefied, halogen substituted alkane such, for example, as methylene chloride. Especially preferred are those halogen substituted alkanes having at least onefiuorine atom in their molecules such as trichlorofluoro-, methane, dichlorodifluoromethane, dichloromonofluoromethane, chlorodifluoromethane, dichlorotetrafluoroethane. In using these blowing agents, they are uniformly distributed in either the polyol reactant or the ,poly- 8 permitting the temperature of the mixture to rise during the ensuing reaction above the boiling point of the liquefied gas so as to produce a porous polyurethane. It should be noted that foaming may also be affected by combining the use of a blowing agent with the addition of Water to the polyol.

EXAMPLE 1 A three-necked flask equipped with a mechanical stirrer, thermometer and distilling head is charged with 268 g. (2.0 moles) of dipropylene glycol, 272.8 g. (2.2 moles) of trimethyl phosphite and 1.0 g. of sodium methoxide. The reactants are then heated slowly to 110 C. A total of 111 g. of volatiles are removed and the reaction mixture is then stripped at 108 C. with aspirator vacuum. The mixture is subsequently cooled and 200 ml. of benbene is added. The reactant mixture is further cooled by means of an ice bath and 176.4 g. (1.2 moles) of chloral is added at a rate sufficient to maintain the pot temperature below about 25 C. The temperature is then raised to C. and aspirator vacuum applied. After the volatiles have been removed, 480.4 grams of a viscous liquid product is obtained. The product is neutral and gives the following'analysis: s

OH numben 28 j P, percent=10.2 (theoretical 10.3%) c1;' erenn=20.7 (theoretical 23.6%).

Infraredanalysis shows that the product contains both vinylphosphate and phosphite groups.

EXAMPLE 2 The procedure of Example 1 is repeated except that 212 g. (2.0 moles) of diethylene glycol is substituted for the dipropylene glycol. The resultant product is a viscous oil having a slightly higher P and Cl content than that of Example 1.

' EXAMPLE 3 The procedure of Example 1 is again repeated except that 384 grams (2.0 moles) of tripropylene glycol is substituted for the dipropylene glycol. The resultant product has a slightly lower P and Cl content than the product of Example 1.

In like manner to the above examples, bromal, monochloroacetone, monobromoacetone, trichloroacetone, tribromoacetone, pentachloroacetone, pentabromoacetone, hexachloroacetone, hexabromoacetone and chloromethyl ethyl ketone give good results when substituted for the chloral in Example 1.

EXAMPLE 4 A 30 gallon reactor fitted with a vacuum distilling column was charged with approximately 26.2 kg. (195 moles) of dipropylene glycol, 26.6 kg. '(214 moles) of trimethyl phosphite and 250 grams of a 25% solution of sodium methylate. The pot temperature was raised from 20 C. to 80 C. over a period of 15 minutes. The temperature was again raised from 80 C. to about 120 C. over 30 minutes and maintained in the range from C. for 45 minutes, during which time a vacuum of 37 mm. was applied. Thereafter about 30 kg. of benzene solvent was added and the temperature was reduced to 54 C. The stepwise addition of 17.4 kg. (118 moles) of chloral was then conducted over a period of 25 minutes while the temperature was allowed to climb to about 69 C. The reactant mixture was allowed to stand for approximately 90 minutes and then vacuum was applied and the temperature was raised to 85 C. over a period of 60 minutes. The final yield was 46.5 kg. of yellow oil having the following properties:

Acid No.=0.14 mg. KOH/g. sample OH No.=20 mg. KOH/ g. sample Cl=23.0%

isoctanate reactant whereupon the reactants are mixed 75 P=9.95%.

9 EXAMPLE A polyurethane foam was prepared by employing the following formulation:

The resultant product was a flexible foam having good color and odor and was self-extinguishing upon heat aging at 140 C. for 22 hours.

What is claimed is:

1. A polyalkylene glycol polyphosphorus composition characterized by an OH number below about 150, and having the formula:

HORO

wherein R is a polyalkylene glycol residue defined as that portion remaining after two hydroxyl groups have been removed from a polyalkylene glycol having the formula:

HOR0H wherein R" is an alkylene group of from 2 to about 20 carbon atoms, which is straight chain, branch chain, or a mixture thereof, and x designates the number of repeating alkylene ether units and is from 2 to about 20; R is selected from the group consisting of hydrogen, C -C alkyl, and C -C haloalkyl, R is a C -C alkyl residue; Y and Z are each selected from the group consisting of hydrogen, halogen, and C -C alkyl; and m and n are numbers in the range from 1 to about 25 such that the sum m-l-n is in the range from about 2 to about 50.

2. The composition of claim 1 wherein R is a residue, as defined in claim 1, of a polyalkylene glycol selected from the group consisting of diethylene glycol, dipropylene glycol and tripropylene glycol.

3. The composition of claim 1 wherein R is selected from the group consisting of hydrogen and methyl and Y and Z are selected from the group consisting of hydrogen and halogen.

4. The composition of claim 1 wherein R is a residue, as defined in claim 1, of a polyalkylene glycol selected from the group consisting of triethylene glycol, dipropylene glycol and tripropylene glycol, R is a C -C alkyl and R is selected from the group consisting of hydrogen and methyl.

5. The composition of claim 1 wherein R is a residue, as defined in claim 1, of dipropylene glycol, R is hydrogen R is methyl, and X and Y are chlorine.

References Cited UNITED STATES PATENTS 3,167,575 1/ 1965 Friedman 260-929 ANTON H. SUTTO, Primary Examiner 'U.S. Cl. X.R.

UNITED STATES PATENT AND TRADEMARK OFFICE CERTIFICATE OF CORRECTION PATENT NO. 3,798,290

DATED March 9, 97

|N\/ ENTOR(S) Kyung S. Shim It is certified that error appears in the ab0ve-identified patent and that said Letters Patent 1 are hereby corrected as shown below:

Column 1, line 67, "retardncy" should read --retardancy-- Column 5, line 57, "members" should read -numbers- Column 7, line 64, after "the' and before "prepared" insert -addition of the polyisocyanate. Alternatively, foams can be-- n n A Column 8, line 16, bene should read --zene-- Column 8, line 57, "120" should read ---lO2- Column 9, line 15, after "upon" insert -dry-- Signed and Scaled this First D y f March 1977 [SEAL] Attest:

RUTH c. MASON c. MARSHALL DANN t Arresting ff Commissioner ufParelzrs and Trademarks 

